A recent study by Factory Mutual Research Corporations
reports that there are THREE main factors influencing
the discharge times of Halon 1301 and alternative systems.
These are Vapour Pressure, Gas Density and Heat of Vaporisation.
Discharge times are reduced as vapour pressure and gas
density decreases as the heat of vaporisation increases.
Hartindo-AF11E has a lower vapour pressure and gas density
than Halon 1301 and a much higher heat of vaporisation,
hence its effectiveness is increased through more efficient
discharge times.
Fine Water Spray / Water Mist
The resulting heavy mist behaves in some
respects like a dense gas but will not diffuse into shielded
areas, consequently each water mist system has to be designed
individually and a requirement may remain for response
team intervention to extinguish small, obstructed fires.
The major difficulties with water mist
systems are those associated with design and engineering.
The requirements to generate, distribute and maintain
adequate concentration of correctly sized droplets throughout
the space may mean that fire protection solutions must
be individually tailored.
Halocarbon Gas System
A number of fire extinguishing halocarbon
gases with zero ozone depletion potential (OOP) have been
developed. These include both MFCs (hydrofluorocarbons)
and PFCs (perfluorocarbons).
| Trade Name |
Designation |
Chemical Formula |
Chemical Name |
| FE-13 |
HFC 23 |
CHF3 |
Trifluoromethane |
| FE-123 |
HFC 125 |
CF3CHF3 |
Pentafluoroethane |
| FM-200 . |
HFC 227ea |
CF3CHFCF3 |
Heptafluoropropane |
| FE-36 |
HFC 236fa |
CF3Ch3CF3 |
Hexafluoropropane |
| CEA-308 |
PFC-2-1-8 |
C3F8 |
Perfluoropropane |
| CEA-410 |
PFC-3-1-10 |
C4F10 |
Perfluorobutane |
None of the agents can be considered as a drop-in replacement
for halon 1301, in the same system. Redesign and modification,
if not replacement, will be required. However, the new
halocarbon agents share many of the characteristics of
halons.
Environmental Aspects; while the MFCs and
PFCs do not affect the ozone layer, they are greenhouse
gases that fall under the Kyoto Protocol and so any release
would count towards the national emissions inventory of
global warming gases. Therefore these gases should only
be used where other safe, technically feasible cost effective
and more environmentally acceptable alternatives do not
exist.
Powders
Powders can create respiratory problems,
they are irritants, corrosive and damaging to delicate
electronic apparatus in protected areas. On discharge
the visibility is
reduced, causing problems with emergency evacuation procedures.
Foam
Most of the foams, seen from an environmental
point of view, are not biodegradable; moreover they could
be toxic to flora and marine fauns. This type of product
causes great damage to every kind of apparatus, making
the eventual clean-up costly.
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